Chemisorption of a thiol-functionalized ruthenium dye on zinc oxide nanoparticles: Implications for dye-sensitized solar cells
نویسندگان
چکیده
ZnO is an alternative to TiO2-based dye-sensitized solar cells (DSSCs). Adsorption of cis-rutheniumbis[2,20-bipyridine]-bis[4-thiopyridine] onto ZnO nanorods has been studied using X-ray and ultraviolet photoelectron spectroscopies (XPS and UPS). XPS indicates chemisorption with a surface density of ca. 1 10 molecules/cm, confirming the possibility of using thiol-terminated dyes for ZnO-based DSSC devices. The energy level diagram, based on UPS and absorbance spectroscopy, indicates that the LUMO of this dye is lower in energy than the ZnO conduction band edge, providing minimal enthalpic driving force for photovoltaic electron injection. However, optimization of thiol-functionalized Ru dyes could result in competitive ZnO-based DSSCs. 2010 Elsevier B.V. All rights reserved.
منابع مشابه
Effect of Acid Etching upon ZnO Anodes in Dye Sensitized Solar Cells
Solar cells must accomplish two basic tasks to generate current: absorb incident photons and conduct excited electrons to the circuit. Traditional solar cells made of silicon accomplish these with a single, expensive material. Dye sensitized solar cells (DSSC) are an alternative using separately optimized materials for each task. In short, a dye absorbs the photons and injects them into a semic...
متن کاملInfluence of nanostructured TiO2 film thickness on photoelectrode structure and performance of flexible Dye- Sensitized Solar Cells
A commercial Ti-Nanoxide was deposited on In-doped SnO2 (ITO) polymer substrates by tape casting technique with different thicknesses (7, 14 and 36μm) to be used as photoelectrode in flexible dye-sensitized solar cells (DSSCs). Ruthenium dye was adsorbed on each TiO2 film for 24 h. The resulting photoelectrodes were used to form flexible DSSCs in combination with...
متن کاملNatural Dye-Sensitized Solar Cells (NDSSCs) From Opuntia Prickly Pear Dye Using ZnO Doped TiO2 Nanoparticles by Sol- Gel Method
Natural dye-sensitized solar cells (NDSSCs) have gained considerable attention in the field of solar energy due to their simple fabrication, good efficiency, and low production cost. Natural dyes are environmentally and economically superior to ruthenium-based dyes because they are nontoxic and cheap. However, the conversion efficiency of dye-sensitized solar cells based on natural dyes is low....
متن کاملInvestigation the effect of substrate photo-electrode based on screen method on performance of dye-sensitized solar cells
In this paper we studied preparation of working films of dye-sensitized solar cells using screen printed method. The organic dye based on phenoltiazine with cyanoacrylic acid as the electron donor group utilized as photosensitizer. Fluorine-doped thin oxide FTO coated glass is transparent electrically conductive and ideal for use in dye-sensitized solar cells. FTO glass was coated by screen pri...
متن کاملApplication of azo dye as sensitizer in dye-sensitized solar cells
An azo dye used as photosensitizers in Dye-sensitized solar cells DSSCs. Azo dyes economically superior to organometallic dyes because they are color variation and cheap. The spectrophotometric evaluation of an azo dye in solution and on a TiO2 substrate show that the dye form J-aggregation on the nanostructured TiO2 substrate. Oxidation potential measurements for used azo dyes ensured an energ...
متن کامل